| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5217390 | Tetrahedron | 2013 | 8 Pages |
Abstract
A facile asymmetric synthesis of Î3-2-Hydroxybakuchiol, Bakuchiol, and ent-Bakuchiol is described through one common intermediate bearing a chiral all-carbon quaternary carbon center, which involves stereoselectively unconjugated alkylation of the α,β-unsaturated imide bearing Evans' auxiliary, Takai-Utimoto reaction, Negishi reaction, and Heck reaction as key steps.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Qian-Qian Xu, Qun Zhao, Guang-Sheng Shan, Xi-Cheng Yang, Qi-Yuan Shi, Xinsheng Lei,