| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5217446 | Tetrahedron | 2013 | 7 Pages |
Abstract
The ambiphilic character of fluorinated radicals was noticed during their radical conjugate addition onto electron-deficient alkenes. Free radicals were trapped with enones when the reaction was conducted from iododifluoro-acetate and -phosphonate derivatives in the presence of Et3B. Competitive addition reaction onto electron-rich or -deficient alkenes was observed depending on the free radical initiator.
Graphical abstractDownload full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Coralie De Schutter, Emmanuel Pfund, Thierry Lequeux,