Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5217557 | Tetrahedron | 2013 | 10 Pages |
Abstract
Fused tetrahydropyrans were synthesized by silver(I)- and mercury(II)-mediated intramolecular hydroalkoxylations of δ-hydroxy allenes installed on a tetrahydropyran template. Cyclization of simple allenes was promoted by silver perchlorate to afford vinyl-substituted trans-fused bis-tetrahydropyrans, whereas cyclization of methyl-substituted allenes at the internal allenic carbon atom was achieved more effectively with a catalytic amount of mercuric triflate rather than with silver salts.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Yumie Suzuki, Ayano Kuwabara, Yasuhiro Koizumi, Yuji Mori,