| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5217603 | Tetrahedron | 2013 | 7 Pages |
Abstract
A practical and eco-friendly aerobic oxidation of homopropargylic alcohols using Fe(NO3)3·9H2O/TEMPO/NaCl as catalysts at room temperature under atmospheric pressure was developed affording corresponding homopropargylic ketones with moderate to good yields. Aryl, heteroaryl as well as alkyl 1,2-allenic ketones were obtained by the isomerization of corresponding terminal homopropargylic ketones through column chromatographic workup on silica gel.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Jinxian Liu, Shengming Ma,