| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5217774 | Tetrahedron | 2013 | 9 Pages |
Abstract
Molybdenum, cobalt, nickel, ruthenium, and rhodium catalyzed alkyne hydrostannations using in situ generated Bu3SnH were studied. In most cases, Bu3SnF+polymethylhydrosiloxane (PMHS) performed well as the in situ source of Bu3SnH. In contrast, the combination of Bu3SnCl/KFaq/PMHS, which had witnessed earlier success in Pd-catalyzed hydrostannation reactions, proved less employable in alkyne hydrostannations mediated by these metals.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Robert E. Jr., Banibrata Ghosh, William P. Gallagher, Aaron J. Baker, Jill A. Muchnij, Amy L. Szymanski,