| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5218021 | Tetrahedron | 2013 | 7 Pages |
Abstract
A synthesis of epoxyquinone natural product cytosporin D from the readily available Diels–Alder adduct of cyclopentadiene and 2-prenyl-p-benzoquinone, has been accomplished. This approach leverages the stereochemical predisposition of the norbornyl-fused systems towards convex face reactivity as an enabler for the stereoselective construction of the pyran ring.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
