| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5218084 | Tetrahedron | 2013 | 11 Pages |
Abstract
The heterobimetallic complex [Ir(COD)(SnCl3)Cl(μ-Cl)]2 catalyzes the aza-Friedel-Crafts reaction of 1,3,5-trimethoxybenzene, as well as substituted indoles with N-sulfonyl aldimines leading to the formation of diarylamines and triarylmethanes in good yields. The symmetrical triarylmethanes were also obtained from diarylamines and suitable nucleophiles via simultaneous cleavage of sp3 C-N bond and elimination of 1,3,5-trimethoxybenzene.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Paresh Nath Chatterjee, Arnab Kumar Maity, Swapna Sarita Mohapatra, Sujit Roy,