Article ID Journal Published Year Pages File Type
5218222 Tetrahedron 2013 5 Pages PDF
Abstract

We have synthesized and fully characterized an acyclic bifunctional vicinal tricarbonyl compound, its hydrate, and its ethanol-adduct, which could be converted to one another by utilizing the reversible addition–elimination of water or ethanol. X-ray single crystal study revealed that the bistriketone expanded and contracted by 10–30% in length during the interconversion.

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Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry