Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5218246 | Tetrahedron | 2013 | 6 Pages |
Abstract
An efficient catalytic system for the palladium-catalyzed oxidative Heck reaction between arylboronic acids and various alkenes has been developed. Using the bis(aminoalkoxy)palladium complex of N,N-dimethylethanolamine as a catalyst, a series of substituted alkenes were obtained in moderate to excellent yields under mild reaction conditions. This protocol could be tolerated to arylboronic acids containing electron-donating or withdrawing groups and a wide range of olefins, such as acrylate, allyl esters, allyl ethers and alkenylphosphonate. A plausible reaction mechanism of the oxidative Heck reaction was proposed.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Xia Mi, Mengmeng Huang, Hai Guo, Yangjie Wu,