Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5218366 | Tetrahedron | 2013 | 10 Pages |
Abstract
Chiral rhodium[bis(oxazolinyl)phenyl] complexes exhibited high catalytic activity for the β-boration of α,β-unsaturated esters, ketones, and amides with bis(pinacolato)diboron in the presence of sodium tert-butoxide to attain high enantioselectivity of up to 97%. The substrate scope and catalytic mechanism were discussed.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Kenji Toribatake, Li Zhou, Ayae Tsuruta, Hisao Nishiyama,