Article ID Journal Published Year Pages File Type
5218444 Tetrahedron 2013 5 Pages PDF
Abstract

A novel asymmetric-axle-supported chiral N-O amide was synthesized and used in catalytic enantioselective hydrosilylation of N-aryl ketimines with HSiCl3 at room temperature instead of the typical −20 °C. High conversion yield and high enantioselectivity up to 96% were observed.

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Physical Sciences and Engineering Chemistry Organic Chemistry
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Highly efficient asymmetric-axle-supported N-O amides in enantioselective hydrosilylation of ketimines with trichlorosilane
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