Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5218454 | Tetrahedron | 2013 | 5 Pages |
Abstract
An efficient strategy for the mechanosynthesis of γ-nitro dicarbonyl esters has been developed. A CaCl2-catalyzed Michael reaction, conducted at room temperature, afforded nitroalkenes from malonates in a short reaction time and in high yields. In most cases, polymerized side-reactions are eliminated or minimized.
Graphical abstractDownload full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Chunman Jia, Da Chen, Chunyan Zhang, Qi Zhang, Bennan Cao, Zhendong Zhao,