Article ID Journal Published Year Pages File Type
5218454 Tetrahedron 2013 5 Pages PDF
Abstract

An efficient strategy for the mechanosynthesis of γ-nitro dicarbonyl esters has been developed. A CaCl2-catalyzed Michael reaction, conducted at room temperature, afforded nitroalkenes from malonates in a short reaction time and in high yields. In most cases, polymerized side-reactions are eliminated or minimized.

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Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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