| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5218530 | Tetrahedron | 2012 | 7 Pages |
Abstract
A facile and effective enantioselective addition of terminal 1,3-diynes to acyclic α-CF3 ketimine esters has been developed by using zinc/Binol complexes. The reaction works well with a variety of aromatic-, aliphatic- and silyl-substituted diynes, providing the desired products in up to 97% yield and 97% enantiomeric excess.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Fa-Guang Zhang, Hai Ma, Yan Zheng, Jun-An Ma,