Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5218604 | Tetrahedron | 2013 | 4 Pages |
Abstract
An efficient synthesis of biaryls using a Hiyama reaction between aryl iodides and aryltrialkoxysilanes in the presence of a diphenylphosphinomethylpolystyrene-supported palladium catalyst is described. The cross-coupling proceeds in the presence of only 0.1 mol % of supported palladium. The catalyst can be used at least four times and the palladium leaching is extremely low (ca. 1% of the initial amount).
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Carine Diebold, Antoine Derible, Jean-Michel Becht, Claude Le Drian,