| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5218816 | Tetrahedron | 2012 | 8 Pages |
Abstract
New ruthenium(II) complexes containing η6-arene-η1-pyrazole ligands were synthesized and characterized by elemental analysis and spectroscopic methods. In addition, the molecular structure of dichloro-3,5-dimethyl-1-(pentamethylbenzyl)-pyrazole–ruthenium(II), [Ru]L3b, was determined by X-ray diffraction studies. These complexes were applied in the transfer hydrogenation of acetophenone by isopropanol in the presence of potassium hydroxide. The activities of the catalysts were monitored by NMR.
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