| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5218924 | Tetrahedron | 2013 | 6 Pages |
Abstract
Fluorocyclization of phenyl-substituted alkenols in ionic liquids under action of N–F reagents namely F-TEDA-BF4 and N-fluorobenzenesulfonimide has been studied. Opposite to the non-stereoselective reaction in organic solvents the reaction in ionic liquids resulted in the formation preferably of the trans-diastereomeric fluorinated cyclic ethers. 2-Difluoromethyl-2-phenyl-tetrahydrofuran was obtained by interaction of 4-phenylpent-4-en-1-ol with F-TEDA-BF4 in ionic liquids.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
