| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5219192 | Tetrahedron | 2012 | 6 Pages |
Abstract
A stereoselective, route to aza-polycyclic systems related to magellanine, and congeners from simple aromatic precursor is described. Oxidative dearomatization leading to a highly reactive spiroepoxycyclohexa-2,4-dienone, intramolecular inverse demand π4s+π2s cycloaddition and photochemical reactions are key features of our approach.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
![Synthesis of 4-aza tricyclo [6.2.2.01,6]dodecenone and photoreactions: a stereoselective, entry to aza-polycyclic systems related to magellanine and congeners](/preview/png/5219192.png "First Page Preview: Synthesis of 4-aza tricyclo [6.2.2.01,6]dodecenone and photoreactions: a stereoselective, entry to aza-polycyclic systems related to magellanine and congeners")