| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5219195 | Tetrahedron | 2012 | 10 Pages |
Abstract
A unified enantioselective route is developed for the synthesis of heptadeca-1-ene-4,6-diyne-3S,8R,9S,10S-tetrol and its synthetic congeners. A proline-catalyzed aminoxylation, cross-metathesis, Wittig reaction, and catalytic dihydroxylation are key steps of this synthesis. This new approach is envisioned to facilitate the synthesis of every representative member of the family with skeletal and stereochemical variation.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Gullapalli Kumaraswamy, Kadivendi Sadaiah,