Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5219236 | Tetrahedron | 2012 | 6 Pages |
Abstract
A new coumarin-derived imine IC1 was designed for highly selective sensing of Zn2+ over Cd2+ ions in aqueous solution based on a controllable CN isomerization mechanism. Methyl as a fine controllable unit was incorporated into IC1 to tune the conformational change of imine and thus significantly improve its selectivity to Zn2+ compared with methyl-free imine IC2. Sensor IC1 was also utilized to image intracellular Zn2+ ions in HepG2 cells with a good performance.
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