Article ID Journal Published Year Pages File Type
5219645 Tetrahedron 2011 7 Pages PDF
Abstract

An efficient method via sequential domino allylation/olefination of C–C triple bonds for the syntheses of five-membered heterocycles was developed by treatment 1,6-enynes with alkenes in the presence of a palladium catalyst. The configurations of the 1,3-dienes of the five-membered heterocycles are stereocontrolled.

Graphical abstractAn efficient method via sequential domino allylation/olefination of C–C triple bonds for the syntheses of five-membered heterocycles was developed by treatment 1,6-enynes with alkenes in the presence of a palladium catalyst. The configurations of the 1,3-dienes of the five-membered heterocycles are stereocontrolled.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry