Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5219645 | Tetrahedron | 2011 | 7 Pages |
Abstract
An efficient method via sequential domino allylation/olefination of C–C triple bonds for the syntheses of five-membered heterocycles was developed by treatment 1,6-enynes with alkenes in the presence of a palladium catalyst. The configurations of the 1,3-dienes of the five-membered heterocycles are stereocontrolled.
Graphical abstractAn efficient method via sequential domino allylation/olefination of C–C triple bonds for the syntheses of five-membered heterocycles was developed by treatment 1,6-enynes with alkenes in the presence of a palladium catalyst. The configurations of the 1,3-dienes of the five-membered heterocycles are stereocontrolled.Figure optionsDownload full-size imageDownload as PowerPoint slide
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