Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5219670 | Tetrahedron | 2012 | 5 Pages |
Abstract
Bidentate phosphine ligands in palladium-catalyzed intramolecular Heck reactions of 2-chloroquinolin-3-yl-(1-homoallyl)alcohols are described to afford facile synthesis of 3-methylene-2,3-dihydro-1H-cyclopenta[b]quinolines in improved yields. We further observed using bulky aromatic phosphine ligand in Pd-catalyzed intermolecular Heck coupling reaction at olefinic centers with iodobenzene also favored exclusively Heck products in excellent yield.
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Authors
Radhey M. Singh, Atish Chandra, Neha Sharma, Bhawana Singh, Ritush Kumar,