| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5219732 | Tetrahedron | 2012 | 6 Pages |
Abstract
α-Triethylsilyl-α-diazoacetone underwent a sequential aldolisation-deprotection-aldolisation process to access the 2-diazo-3-oxo-1,5-dihydroxy skeleton with significant diversity. The diazo group could be efficiently removed by treatment with rhodium acetate to afford the corresponding 5-hydroxy-1,3-diketones.
Graphical abstractDownload full-size image
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Anthony Lancou, Héloua Haroun, Uday K. Kundu, Frédéric Legros, Nicolas Zimmermann, Monique Mathé-Allainmat, Jacques Lebreton, Gilles Dujardin, Catherine Gaulon-Nourry, Pascal Gosselin,