Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5219789 | Tetrahedron | 2011 | 6 Pages |
Abstract
An efficient method for enantioselective synthesis of β-nitrophosphonates via the Michael addition of diphenyl phosphite to nitroalkenes using the readily available quinidine thiourea organocatalyst has been developed. The desired β-nitrophosphonates were obtained in good ee values. Molecular sieves were found to be crucial for achieving high reproducible yields in this reaction.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Santhi Abbaraju, Mayur Bhanushali, Cong-Gui Zhao,