| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5219869 | Tetrahedron | 2012 | 7 Pages |
Abstract
Enantiospecific first total synthesis of the angular triquinane sesquiterpene (6S,7R)-silphiperfolan-6-ol has been accomplished, starting from 2-(3-isopropenyl-2-methylene-1-methylcyclopent-1-yl)acetic acid (readily available from (R)-limonene) employing an efficient, regioselective intramolecular rhodium carbenoid insertion into the CH bond of a tertiary methyl group as the key step.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
A. Srikrishna, Gopalasetty Nagaraju, Vishal M. Sheth,