Article ID Journal Published Year Pages File Type
5219878 Tetrahedron 2012 6 Pages PDF
Abstract

CuCl was found to be an efficient catalyst for the conjugate addition of 2,3-allenoates with Grignard reagents to synthesize poly-substituted β,γ-unsaturated alkenoates with high stereoselectivity in good to excellent yields. Primary, secondary, and tertiary alkyl, vinyl or phenyl Grignard reagents may all be used.

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Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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