| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5219922 | Tetrahedron | 2012 | 9 Pages |
Abstract
The results obtained from a study on the stereochemical control in the dihydroxylation of the double bond of vinyl epoxides and their derivatives (bromo derivatives, azido derivatives and vinyl aziridines) are presented herein. A significant diastereoselectivity was observed for the bromo derivatives, azido derivatives and N-protected vinyl aziridines, whereas vinyl epoxides and unprotected vinyl aziridines showed no diastereoselectivity. The results obtained are generally consistent with the Kishi model.
Graphical abstractDownload full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Giuliana Righi, Emanuela Mandic', Gaia Clara Mercedes Naponiello, Paolo Bovicelli, Ilaria Tirotta,