Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5219929 | Tetrahedron | 2012 | 10 Pages |
Abstract
Enantiospecific total synthesis of the crinipellin mentioned in the title was accomplished. In the present synthesis cyclopentane ring in campholenaldehyde was identified as the B-ring, two intramolecular rhodium carbenoid CH insertion reactions were employed for the construction of the A and C rings, and an intramolecular Michael addition reaction was utilized for the construction of the D-ring of crinipellin.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
A. Srikrishna, V. Gowri,