Article ID Journal Published Year Pages File Type
5220065 Tetrahedron 2012 6 Pages PDF
Abstract

The synthesis of anomeric thiocyanates with the α- and β-configuration is described. Reactions performed under standard conditions afforded the 1,2-trans derivatives as the main products, whereas in the presence of the quaternary ammonium salts, the 1,2-cis-thiocyanates were formed preferentially. The strong influence of the bromide ions on the distribution of the products is discussed.

Graphical abstractDownload full-size image

Keywords
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
Authors
, ,