Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5220213 | Tetrahedron | 2012 | 7 Pages |
Abstract
Asymmetric first total synthesis of eudistomidins G, H, and I, tetrahydro-β-carboline alkaloids from the Okinawan marine tunicate Eudistoma glaucus, has been accomplished with the Bischler-Napieralski reaction and the Noyori catalytic asymmetric hydrogen-transfer reaction. The absolute configurations of eudistomidins G, H, and I were confirmed from comparison of the 1H and 13C NMR, and CD spectral data of synthetic and natural eudistomidins G, H, and I, respectively.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Haruaki Ishiyama, Kazuaki Yoshizawa, Jun'ichi Kobayashi,