| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5220569 | Tetrahedron | 2012 | 4 Pages |
Abstract
The natural product angelone was readily accessed with a remarkable biomimetic journey that sequentially features carbonyl formation-elimination, 6Ï-electrocyclization, visible light-promoted singlet O2 Diels-Alder reaction, Kornblum-DeLaMare-type peroxide rearrangement, 6Ï-electrocyclic ring-opening, and conjugative addition-elimination as the key steps. With key intermediates isolated and characterized, this study stands to reveal a rare system in which bio-inspired synthetic strategies were found to mirror experimental realities.
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Related Topics
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Authors
Haibo Tan, Xinzheng Chen, Zheng Liu, David Zhigang Wang,