Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5220696 | Tetrahedron | 2011 | 10 Pages |
Abstract
The reverse amidohelicene (P)-tetramer containing (P)-helicenediamine and m-phenylenedicarboxylate was synthesized. The circular dichroism (CD) and vapor pressure osmometry (VPO) analysis revealed the dimeric aggregate formation in THF. It is notable that the reverse amide tetramer formed a duplex, as well as the original amidohelicene oligomers. In various solutions, mixtures of the reverse (P)-tetramer and amidohelicene (P)/(M)-tetramer formed homoaggregates instead of heteroaggregates.
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