Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5220852 | Tetrahedron | 2011 | 5 Pages |
Abstract
α,β-Unsaturated acids, through their acid chlorides, react with tritylamine in the presence of triethylamine under mild conditions, to afford in high yield and high regioselectivity the corresponding β,γ-unsaturated tritylamides. Detritylation with TFA generates quantitatively β,γ-unsaturated primary amides. An investigation of this deconjugative isomerization was performed.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Vassiliki Theodorou, Marina Gogou, Maria Philippidou, Valentine Ragoussis, Georgios Paraskevopoulos, Konstantinos Skobridis,