Article ID Journal Published Year Pages File Type
5220933 Tetrahedron 2011 7 Pages PDF
Abstract

A new class of palladium(II) complexes of chelating NHC–N donor hybrid ligands, such as NHC–sulfonamide (6), NHC–phenoxyimine (11), NHC–phenylimine (14), and NHC–amine (15) have been successfully synthesized in modest yields from 1,1′-binaphthyl-2,2′-diamine (BINAM). These complexes have been characterized by all the spectroscopic data, and the structures of 6, 11, and 14 were also confirmed by single-crystal X-ray diffraction studies, exhibiting a tridentate chelating motif around the palladium center.

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Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry