Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5220933 | Tetrahedron | 2011 | 7 Pages |
Abstract
A new class of palladium(II) complexes of chelating NHC–N donor hybrid ligands, such as NHC–sulfonamide (6), NHC–phenoxyimine (11), NHC–phenylimine (14), and NHC–amine (15) have been successfully synthesized in modest yields from 1,1′-binaphthyl-2,2′-diamine (BINAM). These complexes have been characterized by all the spectroscopic data, and the structures of 6, 11, and 14 were also confirmed by single-crystal X-ray diffraction studies, exhibiting a tridentate chelating motif around the palladium center.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry