Article ID Journal Published Year Pages File Type
5221030 Tetrahedron 2012 7 Pages PDF
Abstract

The enhancement of the electron transfer processes in the Grignard reagent formation-type ring silylation and the defluorination-silylation of perfluoroalkyl benzenes by Cu(0)-deposited Mg metal were confirmed. Microscopic analysis and substituent effects implied a different reduction process in the presence of Cu-deposited Mg metal than in the presence of bare Mg metal.

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Physical Sciences and Engineering Chemistry Organic Chemistry
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