Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5221030 | Tetrahedron | 2012 | 7 Pages |
Abstract
The enhancement of the electron transfer processes in the Grignard reagent formation-type ring silylation and the defluorination-silylation of perfluoroalkyl benzenes by Cu(0)-deposited Mg metal were confirmed. Microscopic analysis and substituent effects implied a different reduction process in the presence of Cu-deposited Mg metal than in the presence of bare Mg metal.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Shinya Utsumi, Toshimasa Katagiri, Kenji Uneyama,