| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5221082 | Tetrahedron | 2010 | 4 Pages |
Abstract
α-Trifluoromethylallenic phosphonates were prepared by the reaction of diethyl chlorophosphite (DECP) and 4,4,4-trifluorobut-2-yn-1-ols in the presence of Et3N. The iodocyclization of these fluorine-containing allenic phosphonates was achieved with iodine under mild conditions to give the corresponding trifluoromethylated oxaphospholenes in moderate to good yields.
Graphical abstractDownload full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Peng Li, Zhen-Jiang Liu, Jin-Tao Liu,