Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5221174 | Tetrahedron | 2012 | 6 Pages |
Abstract
Sphos (2-dicyclohexylphosphino-2â²,6â²-dimethoxy-1,1â²-biphenyl) adduct of cyclopalladated ferrocenylimine (IIe) exhibited highly catalytic activity for the Suzuki cross-coupling reaction of cyclopropylboronic acid with aryl(het) halides with 1 mol % catalyst loading. This process was applied to both of aryl and heteroaryl halides (Br and Cl), and made the various arylcyclopropane and heteroarylcyclopropane to be easily synthesized. A variety of substituents on the aryl halides, such as alkyl, acetyl, benzoyl, ether, formyl, carboxylate, methoxy, nitro and cyano were tolerated.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Min Zhang, Xiuling Cui, Xiaopei Chen, Lianhui Wang, Jingya Li, Yusheng Wu, Lifen Hou, Yangjie Wu,