| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5221217 | Tetrahedron | 2010 | 8 Pages |
Abstract
The C14-C24 fragment of symbiodinolide possessing the 17R/18R/21R absolute configuration, which was obtained as one of the degraded products of symbiodinolide, and its diastereomer possessing the 17R/18S/21R absolute stereochemistry were synthesized stereoselectively from cis-2-butene-1,4-diol, respectively. The detailed comparison of the synthetic products with the degraded product in the spectroscopic data confirmed unambiguously that the stereostructure of the C14-C24 fragment was 17R, 18R, and 21R.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Hiroyoshi Takamura, Yuichiro Kadonaga, Isao Kadota, Daisuke Uemura,