Article ID Journal Published Year Pages File Type
5221319 Tetrahedron 2012 4 Pages PDF
Abstract

Reductive defluorination-silylation of alkyl trifluoroacetates with copper-deposited magnesium and trimethylsilyl chloride (TMS-Cl) gave 2,2-difluoro-2-(trimethylsilyl)acetates, potential difluoromethylene building blocks, in 60-68% yields.

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Physical Sciences and Engineering Chemistry Organic Chemistry
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Defluorination-silylation of alkyl trifluoroacetates to 2,2-difluoro-2-(trimethylsilyl)acetates by copper-deposited magnesium and trimethylsilyl chloride
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