Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5221667 | Tetrahedron | 2011 | 5 Pages |
Abstract
An oxidative cleavage of allyl vic-diols to aldehydes catalyzed by a Grubbs carbene complex using a co-oxidant has been established for the first time, with good yields. The utility of this selective cleavage reaction was demonstrated through the use of two huge marine molecules, symbiodinolide and N-p-BrBz palytoxin.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Chunguang Han, Yoshi Yamano, Fumitoshi Kakiuchi, Kazuhiko Nakamura, Daisuke Uemura,