Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5221711 | Tetrahedron | 2010 | 10 Pages |
Abstract
Bromide and chloride derivatives of Baylis-Hillman adducts have been demonstrated to react efficiently with triarylbismuths affording allylic arylated products in high yields under palladium-catalyzed conditions. Triarylbismuths have been employed in sub-stoichiometric amounts as multi-coupling and atom-efficient nucleophiles in these reactions. The reactivity of both allylic bromides and chlorides was found to be facile and equally efficient in couplings with triarylbismuths.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Maddali L.N. Rao, Debasis Banerjee, Ritesh J. Dhanorkar,