| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5221842 | Tetrahedron | 2011 | 5 Pages |
Abstract
The stereoselective synthesis of C12 oxygenated marine scalaranic sesterterpene 16-deacetoxy-12-epi-scalarafuran acetate and its 14-epimer were described. A highly stereoselective intramolecular Diels-Alder addition was designed as the key step to construct the ring D, and the absolute configurations of natural 16-deacetoxy-12-epi-scalarafuran acetate was supported by the X-ray diffraction analysis of single crystal of corresponding 16-deacetoxy-12-epi-scalarafuran.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Zheng-Lin Wang, Zi-Gang Zhang, Hong-Chang Li, Wei-Ping Deng,