Article ID Journal Published Year Pages File Type
5222028 Tetrahedron 2011 6 Pages PDF
Abstract

We report herein the design and synthesis of two new quadrupolar D-π-A-π-D chromophores containing diphenyl amine and dicyanobenzene or 2,1,3-benzothiadiazole as electron donor (D) and acceptor (A), respectively, which are bridged by fluorene linkage (π). The introduction of coplanar fluorenes is highly beneficial for the enhancement of two-photon absorption (TPA), where 1b displays a TPA cross section (σ2) of up to 1975±207 GM.

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Physical Sciences and Engineering Chemistry Organic Chemistry
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