Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5222048 | Tetrahedron | 2011 | 7 Pages |
Abstract
The divergent syntheses of the spirocyclic pyran core of polymaxenolide and the spirocyclic piperidine core of pinnaic acid have been achieved. Our divergent approach takes advantage of highly efficient Achmatowicz and aza-Achmatowicz rearrangements to generate the highly functionalised cores, which are then regioselectively modified.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Frank D. Ferrari, Andrew J. Ledgard, Rodolfo Marquez,