Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5222051 | Tetrahedron | 2011 | 10 Pages |
Abstract
A highly diastereoselective iron-catalyzed synthesis of substituted cis-2,6-tetrahydropyrans from ζ-hydroxy allylic derivatives is described. The FeCl3·6H2O-induced epimerization of the formed 2-alkenyl 6-substituted tetrahydropyrans is the key reaction to account for the high diastereoselectivities observed.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Amandine Guérinot, Anna Serra-Muns, Charlélie Bensoussan, Sébastien Reymond, Janine Cossy,