Article ID Journal Published Year Pages File Type
5222268 Tetrahedron 2011 6 Pages PDF
Abstract

A Pd/bipy-based catalytic system for the C–H bond arylation of heteroarenes with haloarenes is described. The complex PdBr2(bipy)·DMSO, whose structure was unambiguously determined by X-ray crystallography, turned out to be a general catalyst precursor for the process. The reaction is applicable to a range of electron-rich five-membered heteroarenes, such as thiophenes, thiazoles, benzofurans, and indoles.

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Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry