Article ID Journal Published Year Pages File Type
5222318 Tetrahedron 2011 8 Pages PDF
Abstract

Salmochelin S1, S2, MGE, DGE, and TGE were prepared through amide bond connection of an aryl C-glucosyl acyl chloride (Ar1COCl) and serine ester amines, followed by hydrogenolysis of the per-benzylated precursors. Each synthesis employed a highly diastereoselective Ni-catalyzed Negishi approach to the aryl C-glycoside subunit.

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Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry