Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5222318 | Tetrahedron | 2011 | 8 Pages |
Abstract
Salmochelin S1, S2, MGE, DGE, and TGE were prepared through amide bond connection of an aryl C-glucosyl acyl chloride (Ar1COCl) and serine ester amines, followed by hydrogenolysis of the per-benzylated precursors. Each synthesis employed a highly diastereoselective Ni-catalyzed Negishi approach to the aryl C-glycoside subunit.
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