| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5222428 | Tetrahedron | 2009 | 5 Pages |
Abstract
Difluorocarbene generated from FSO2CF2CO2SiMe3 (TFDA) at 120 °C could reacted with terminal alkynes having an ester group at the α position to the triple bond. Difluorocyclopropenes were further converted to difluorocyclopropyl ketones under alkaline condition. Mechanism for the conversion was studied.
Graphical abstractDownload full-size image
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Xiao-Chun Hang, Wei-Peng Gu, Qing-Yun Chen, Ji-Chang Xiao,