| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5222629 | Tetrahedron | 2010 | 9 Pages |
Abstract
High yielding synthesis of six- and five-membered N-substituted iminosugar glycosides and of five-membered iminosugar thioglycosides by nucleophilic opening of both new and previously described N-diethoxycarbonylvinyl anhydroiminosugar derivatives (glycosyl donors) with primary alcohols, primary thiols, and thiophenol (glycosyl acceptors) is reported. The reactions are highly stereoselective, with anomeric ratios better than 4:1.
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