Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5222908 | Tetrahedron | 2010 | 4 Pages |
Abstract
New stable [6,6]-methano cycloadducts and fulleropyrazolines containing electron-withdrawing groups have been obtained by the reaction of ethyl diazopyruvate with [60]fullerene. The results obtained by a systematic study conducted both in thermal and catalytic conditions have provided crucial indications concerning the mechanism of this important cluster opening process in fullerene chemistry.
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