Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5223049 | Tetrahedron | 2010 | 9 Pages |
Abstract
Several new five- and a six-membered heterocyclic monochloroiodanes, including two cationic species, were synthesized. Three of which were used for the preparation of corresponding trifluoromethylation reagents. These compounds were characterized by X-ray crystallography for a comparative structural study. A reactivity study on the trifluoromethylation of para-toluenesulfonic acid has been conducted in order to compare initial rates. Compounds having a longer I–O bond display a higher reactivity.
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